Sorting carbon nanotubes via dielectrophoresis
R. Krupke, F. Hennrich
Whenever the electronic properties of carbon nanotubes matter, it is beneficial
to use single-walled carbon nanotubes, which have been sorted by their
metallicity. Dielectrophoresis at high electrical-field frequency allows to sort
out the metallic tubes from a mixed suspension [1]. The theoretical modelling of
the process predicts the yield of separation to be intrinsically at 100% [2,3].
Experimentally this yield is affected by the residual bundle content of the
nanotube suspension, the electrical-field frequency and the surfactant content.
We will present the optimum conditions for separation. Due to our recent
progress in upscaling the method, we are now able to base our analysis on
optical absorption spectroscopy in addition to resonant Raman spectroscopy.
References:
1] R. Krupke, F, Hennrich, H.
v. Löhneysen, M. M. Kappes, Science 301 (2003) 344
[2] R. Krupke, F. Hennrich, M. M. Kappes, H. v. Löhneysen, Nano Lett. 4 (2004)
1395
[3] R. Krupke, F. Hennrich, Adv. Eng. Mater. 2005
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