Mass Production, Applications and Structural Controllability of
Carbon Nanotubes by Catalytic CVD (CCVD) Method
Multi walled carbon nanotubes (MWNTs) have been successfully produced by
large-scale production system based on CVD method using Fe catalyst [1,2]. The
diameters are in the range of several 10 nm or less and have provided different
mechanical as well as electronic properties than those of conventional carbons.
The commercially available NT's have been applied and contributing to lithium
ion battery technology, sporting goods, NT based carbon composite for advanced
audio speaker cones. It is also expected to be applied as a micro-catheter
(inner diameter 0.43mm, outer diameter 0.53mm) made by resin/high-purity NT
composite with enhanced mechanical properties (easier to handle) and extremely
reduced thrombogenicity [3].
Based on the present CCVD process, controllable growth of double-walled carbon
nanotubes (DWNTs) has been established, because it is expected that DWNTs are
expected to have striking new electronic and mechanical properties, which is
also very promising for specified applications. Here, we fabricate a paper-like
material that consists of hexagonally packed bundles of clean, coaxial carbon
nanotubes whose double walls vary little in diameter [1,2,4]. Also demonstrated
are the coalescence of DWNTs [5], and a novel structure consisting of flattened
tubules containing two SWNTs (bicable) [5].
It is envisaged that carbon nanotubes will take an important place in the
development of emerging technologies in near future.
The author would like to thank Prof. M.S.Dresselhaus, Prof. M.Terrones, Prof.
H.W.Kroto and Drs. T.Hayashi, Y.A.Kim for their helpful discussion and
collaboration.
References
(1) A. Oberlin, M. Endo, T. Koyama. J. Cryst. Growth 32, 335 (1976).
(2) M. Endo. Chem. Tech. 568 (1988).
(3) M. Endo, S. Koyama, Y. Matsuda, T. Hayashi, and Y. A. Kim, Nano Letters 5,
101 (2005).
(4) M. Endo, H. Muramatsu, T. Hayashi, Y. A. Kim, M. Terrones, M. S. Dresselhaus,
Nature 433, 476 (2005).
(5) M. Endo, T. Hayashi, H. Muramatsu, Y. A. Kim, H. Terrones, M. Terrones, and
M. S. Dresselhaus, Nano Letters 4, 1451 (2004).
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