| Equipment
Mass spectrometer
The main tool that we use to study the dynamics of excited fullerenes is
a reflectron time-of-flight mass spectrometer (ReToF). In the ReToF we can
excite fullerenes evaporated from an oven and mass separate the produced ions.
To find out more about the mass spectrometer click
here.
The Cold Source
We also have the possibility to produce vibrationally cold fullerenes or
clusters of fullerenes (or clusters of other molecules too for that matter).
This is done in a gas aggregation source called the Cold Source. The cold
molcules can then be excited and analyzed in the ReToF. More about the Cold
Source here.
Lasers
To excite our fullerenes we mainly use pulsed lasers. At our disposal we
have one N2 laser which gives a wavelength of 337 nm
(3.7 eV), an ArF laser which gives 193 nm (6.4 eV), an OPO
system which can be tuned between 230 and 2000 nm and a femto second
laser system. The ArF laser, which
is an excimer laser, can also be used with a F2 gas mix and then
gives 157 nm (7.9 eV). With such a high photon energy it is possible to one
photon ionise C60 (which has an ionisation energy of 7.6 eV).
The fs laser system can work at the fundamental, ca 800 nm, plus the second and
third harmonic producing pulses of ca 150 fs. We also have a NOPA which makes it
possible to the wavelength from ca 250-1600 nm. The output from the NOPA has a
pulselength of ca 20-30 fs.
In addition to the lasers we have a filament which emits electrons making
it possible to excite and ionise fullerenes by electron impact.
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